Synthesis of Functionalized Tris(2-propoxyphenyl)phosphine Oxides as Precursors of Tripodal Propeller-Shaped Ligands
- Авторлар: Baulina Т.1, Kudryavtsev I.1, Sykat G.1, Brel’ V.1
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Мекемелер:
- Nesmeyanov Institute of Organoelement Compounds
- Шығарылым: Том 88, № 9 (2018)
- Беттер: 1927-1930
- Бөлім: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/222433
- DOI: https://doi.org/10.1134/S1070363218090281
- ID: 222433
Дәйексөз келтіру
Аннотация
A series of precursors of novel tripodal ligands (2-XCH2CH2CH2OC6H4)3PO, where X = AcO, HO, MeSO2O, Br, N3, were synthesized by the alkylation of the starting tris(2-hydroxyphenyl)phosphine oxide with 3-bromopropyl acetate followed by hydrolysis of the resulting triacetate to triol and conversion of the latter to trimesylate. Treratment of the resulting trimesylate with LiBr or NaN3 was used to prepare the corresponding tribromo or triazido derivatives.
Авторлар туралы
Т. Baulina
Nesmeyanov Institute of Organoelement Compounds
Хат алмасуға жауапты Автор.
Email: zaq@ineos.ac.ru
Ресей, ul. Vavilova 28, Moscow, 119991
I. Kudryavtsev
Nesmeyanov Institute of Organoelement Compounds
Email: zaq@ineos.ac.ru
Ресей, ul. Vavilova 28, Moscow, 119991
G. Sykat
Nesmeyanov Institute of Organoelement Compounds
Email: zaq@ineos.ac.ru
Ресей, ul. Vavilova 28, Moscow, 119991
V. Brel’
Nesmeyanov Institute of Organoelement Compounds
Email: zaq@ineos.ac.ru
Ресей, ul. Vavilova 28, Moscow, 119991