Rearrangements and Tautomeric Transformations of Heterocyclic Compounds in Homogeneous Reaction Systems Furfural–Н2О2–Solvent
- Авторлар: Badovskaya L.1, Poskonin V.1
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Мекемелер:
- Kuban State Technological University
- Шығарылым: Том 88, № 8 (2018)
- Беттер: 1568-1579
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222349
- DOI: https://doi.org/10.1134/S1070363218080030
- ID: 222349
Дәйексөз келтіру
Аннотация
General information on the reactions of furfurals with hydrogen peroxide is given. We have discussed the Baeyer–Villiger rearrangement of furan 2-hydroxyhydroperoxides and tautomeric transformations with proton transfer of 2-hydroxyfuran and β-formylacrylic acid formed in a homogeneous reaction system furfural–Н2О2–solvent under the catalysis with the formed acids. The factors affecting these rearrangements and tautomeric transformations as well as their specificity in comparison with benzene type compounds, and the pathway of the reactions of furan aldehydes with Н2О2 in water have been analyzed. Ketoenol tautomerism of cyclic hemiacetal form of β-formylacrylic acid leading to its transformation into succinic anhydride has been described for the first time.
Авторлар туралы
L. Badovskaya
Kuban State Technological University
Email: vposkonin@mail.ru
Ресей, ul. Moskovskaya 2, Krasnodar, 350072
V. Poskonin
Kuban State Technological University
Хат алмасуға жауапты Автор.
Email: vposkonin@mail.ru
Ресей, ul. Moskovskaya 2, Krasnodar, 350072