Chemical and Electrochemical Synthesis, Structure, and Properties of Metal Chelates of Tridentate N,S-Containing Azomethinazo Ligands
- Авторлар: Burlov A.1, Mashchenko S.1, Vlasenko V.2, Nikolaevskii S.3, Kiskin M.3, Zubavichus Y.4, Uraev A.1, Garnovskii D.5, Korshunova E.1, Levchenkov S.5
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Мекемелер:
- Research Institute of Physical and Organic Chemistry
- Research Institute of Physics
- Kurnakov Institute of General and Inorganic Chemistry
- Kurchatov Institute National Research Center
- Southern Research Center
- Шығарылым: Том 88, № 2 (2018)
- Беттер: 262-270
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221996
- DOI: https://doi.org/10.1134/S1070363218020123
- ID: 221996
Дәйексөз келтіру
Аннотация
Novel Cu(II), Co(II), Ni(II), and Zn(II) complexes of 5-methyl-2-phenyl-4-[(4-phenylazo)anilinemethylylidene]- 2,4-dihydro-3H-pyrazole-3-thione and 5-methyl-4-[4-methyl-2-(4-methylphenylazo)anilinemethylylidene]- 2-phenyl-2,4-dihydro-3H-pyrazole-3-thione, i.e. ligands containing the phenylazo group in the ortho and para positions of the aniline fragment, were synthesized by the chemical and electrochemical methods. The complexes and ligands were characterized by IR, 1H NMR, X-ray absorption spectroscopy and magnetochemistry. The azo group of the ligands is not involved in coordination to the metal.
Негізгі сөздер
Авторлар туралы
A. Burlov
Research Institute of Physical and Organic Chemistry
Хат алмасуға жауапты Автор.
Email: anatoly.burlov@yandex.ru
Ресей, pr. Stachki 194/2, Rostov-on-Don, 344090
S. Mashchenko
Research Institute of Physical and Organic Chemistry
Email: anatoly.burlov@yandex.ru
Ресей, pr. Stachki 194/2, Rostov-on-Don, 344090
V. Vlasenko
Research Institute of Physics
Email: anatoly.burlov@yandex.ru
Ресей, Rostov-on-Don
S. Nikolaevskii
Kurnakov Institute of General and Inorganic Chemistry
Email: anatoly.burlov@yandex.ru
Ресей, Moscow
M. Kiskin
Kurnakov Institute of General and Inorganic Chemistry
Email: anatoly.burlov@yandex.ru
Ресей, Moscow
Ya. Zubavichus
Kurchatov Institute National Research Center
Email: anatoly.burlov@yandex.ru
Ресей, Moscow
A. Uraev
Research Institute of Physical and Organic Chemistry
Email: anatoly.burlov@yandex.ru
Ресей, pr. Stachki 194/2, Rostov-on-Don, 344090
D. Garnovskii
Southern Research Center
Email: anatoly.burlov@yandex.ru
Ресей, Rostov-on-Don
E. Korshunova
Research Institute of Physical and Organic Chemistry
Email: anatoly.burlov@yandex.ru
Ресей, pr. Stachki 194/2, Rostov-on-Don, 344090
S. Levchenkov
Southern Research Center
Email: anatoly.burlov@yandex.ru
Ресей, Rostov-on-Don