Chemical and Electrochemical Synthesis, Structure, and Properties of Metal Chelates of Tridentate N,S-Containing Azomethinazo Ligands
- Authors: Burlov A.S.1, Mashchenko S.A.1, Vlasenko V.G.2, Nikolaevskii S.A.3, Kiskin M.A.3, Zubavichus Y.V.4, Uraev A.I.1, Garnovskii D.A.5, Korshunova E.V.1, Levchenkov S.I.5
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Affiliations:
- Research Institute of Physical and Organic Chemistry
- Research Institute of Physics
- Kurnakov Institute of General and Inorganic Chemistry
- Kurchatov Institute National Research Center
- Southern Research Center
- Issue: Vol 88, No 2 (2018)
- Pages: 262-270
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221996
- DOI: https://doi.org/10.1134/S1070363218020123
- ID: 221996
Cite item
Abstract
Novel Cu(II), Co(II), Ni(II), and Zn(II) complexes of 5-methyl-2-phenyl-4-[(4-phenylazo)anilinemethylylidene]- 2,4-dihydro-3H-pyrazole-3-thione and 5-methyl-4-[4-methyl-2-(4-methylphenylazo)anilinemethylylidene]- 2-phenyl-2,4-dihydro-3H-pyrazole-3-thione, i.e. ligands containing the phenylazo group in the ortho and para positions of the aniline fragment, were synthesized by the chemical and electrochemical methods. The complexes and ligands were characterized by IR, 1H NMR, X-ray absorption spectroscopy and magnetochemistry. The azo group of the ligands is not involved in coordination to the metal.
About the authors
A. S. Burlov
Research Institute of Physical and Organic Chemistry
Author for correspondence.
Email: anatoly.burlov@yandex.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
S. A. Mashchenko
Research Institute of Physical and Organic Chemistry
Email: anatoly.burlov@yandex.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
V. G. Vlasenko
Research Institute of Physics
Email: anatoly.burlov@yandex.ru
Russian Federation, Rostov-on-Don
S. A. Nikolaevskii
Kurnakov Institute of General and Inorganic Chemistry
Email: anatoly.burlov@yandex.ru
Russian Federation, Moscow
M. A. Kiskin
Kurnakov Institute of General and Inorganic Chemistry
Email: anatoly.burlov@yandex.ru
Russian Federation, Moscow
Ya. V. Zubavichus
Kurchatov Institute National Research Center
Email: anatoly.burlov@yandex.ru
Russian Federation, Moscow
A. I. Uraev
Research Institute of Physical and Organic Chemistry
Email: anatoly.burlov@yandex.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
D. A. Garnovskii
Southern Research Center
Email: anatoly.burlov@yandex.ru
Russian Federation, Rostov-on-Don
E. V. Korshunova
Research Institute of Physical and Organic Chemistry
Email: anatoly.burlov@yandex.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
S. I. Levchenkov
Southern Research Center
Email: anatoly.burlov@yandex.ru
Russian Federation, Rostov-on-Don