Model of Solvation and Association Processes in Non-Electrolytes Solutions


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Abstract

A model of a solution of non-electrolytes has been considered, which is a superposition of equilibrium processes of solvation, homo- and heteroassociation. The chemical potentials and activity coefficients of the components have been calculated for a binary solution considering only symmetric solvation. The model has been verified to calculate the density of binary solutions with high agreement with experimental data.

About the authors

Yu. E. Zevatsky

St. Petersburg State Institute of Technology (Technical University); V.I. Ulyanov (Lenin) St. Petersburg State Electrotechnical University “LETI,”; Novbytkhim

Author for correspondence.
Email: yuri@newchem.ru
Russian Federation, St. Petersburg, 190013; St. Petersburg, 197022; Gatchina, 188304


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