Benzene Alkylation with Cycloolefins under the Action of [Et3NH]+[Al2Cl7]− Ionic Liquid
- Authors: Aminov R.I.1, Mazitova A.S.1, Khusnutdinov R.I.1
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Affiliations:
- Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences
- Issue: Vol 89, No 11 (2019)
- Pages: 2171-2177
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223144
- DOI: https://doi.org/10.1134/S107036321911001X
- ID: 223144
Cite item
Abstract
Benzene alkylation with mono- and bicyclic olefins under the action of an inorganic ionic liquid [Et3NH]+[Al2Cl7]− with the formation of benzene cycloalkyl derivatives in 58–98% yield has been performed for the first time. It has been found that the increase in the olefin cycle size improves the selectivity with respect to monocycloalkyl derivatives.
Keywords
About the authors
R. I. Aminov
Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences
Author for correspondence.
Email: inklab4@gmail.com
Russian Federation, Ufa, 450075
A. S. Mazitova
Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences
Email: inklab4@gmail.com
Russian Federation, Ufa, 450075
R. I. Khusnutdinov
Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences
Email: inklab4@gmail.com
Russian Federation, Ufa, 450075