Benzene Alkylation with Cycloolefins under the Action of [Et3NH]+[Al2Cl7] Ionic Liquid


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Abstract

Benzene alkylation with mono- and bicyclic olefins under the action of an inorganic ionic liquid [Et3NH]+[Al2Cl7] with the formation of benzene cycloalkyl derivatives in 58–98% yield has been performed for the first time. It has been found that the increase in the olefin cycle size improves the selectivity with respect to monocycloalkyl derivatives.

About the authors

R. I. Aminov

Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences

Author for correspondence.
Email: inklab4@gmail.com
Russian Federation, Ufa, 450075

A. S. Mazitova

Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences

Email: inklab4@gmail.com
Russian Federation, Ufa, 450075

R. I. Khusnutdinov

Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences

Email: inklab4@gmail.com
Russian Federation, Ufa, 450075


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