Alkoxytelluration of Styrene with Tellurium Tetrahalides
- Authors: Potapov V.A.1, Khabibulina A.G.1, Udalova S.I.1, Musalov M.V.1, Musalova M.V.1, Shkurchenko I.V.2, Albanov A.I.1, Amosova S.V.1
-
Affiliations:
- A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
- Irkutsk State University
- Issue: Vol 89, No 10 (2019)
- Pages: 2154-2158
- Section: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/223139
- DOI: https://doi.org/10.1134/S107036321910027X
- ID: 223139
Cite item
Abstract
An efficient synthesis of the earlier unknown trichloro- and tribromo(2-ahkoxy-2-phenylethyl)-λ4-tellanes with yields of 90 to 100% has been developed basing on alkoxytelluration of styrene with tellurium tetrachloride or tetrabromide in the presence of alcohols. The reduction of tellanes in the NaBH4-H2O-THF and Na2S2O5-H2O-C6H6 systems has afforded bis(2-alkoxy-2-phenylethyl)ditellanes in up to 95% yield.
About the authors
V. A. Potapov
A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Author for correspondence.
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
A. G. Khabibulina
A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
S. I. Udalova
A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
M. V. Musalov
A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
M. V. Musalova
A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
I. V. Shkurchenko
Irkutsk State University
Email: v_a_potapov@irioch.irk.ru
Russian Federation, Irkutsk
A. I. Albanov
A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
S. V. Amosova
A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033