Mechanically Activated Solid-Phase Reaction of Copper(I) Chloride with Sodium β-Diketonates: Formation of Metallic Copper Nanoparticles
- Authors: Makhaev V.D.1, Petrova L.A.1, Shulga Y.M.1
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Affiliations:
- Institute of Problems of Chemical Physics
- Issue: Vol 89, No 7 (2019)
- Pages: 1447-1450
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222993
- DOI: https://doi.org/10.1134/S1070363219070156
- ID: 222993
Cite item
Abstract
Solid-phase reaction of copper(I) chloride with sodium β-diketonates under mechanical activation in a vibration ball mill involves disproportionation of CuCl with the formation of the corresponding copper(II) β-diketonate and highly reactive X-ray amorphous metallic copper nanoparticles. The effect of reaction conditions on the process and some properties of the activated mixtures have been studied.
About the authors
V. D. Makhaev
Institute of Problems of Chemical Physics
Author for correspondence.
Email: vim@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast
L. A. Petrova
Institute of Problems of Chemical Physics
Email: vim@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast
Yu. M. Shulga
Institute of Problems of Chemical Physics
Email: vim@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast