Mechanically Activated Solid-Phase Reaction of Copper(I) Chloride with Sodium β-Diketonates: Formation of Metallic Copper Nanoparticles


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Abstract

Solid-phase reaction of copper(I) chloride with sodium β-diketonates under mechanical activation in a vibration ball mill involves disproportionation of CuCl with the formation of the corresponding copper(II) β-diketonate and highly reactive X-ray amorphous metallic copper nanoparticles. The effect of reaction conditions on the process and some properties of the activated mixtures have been studied.

About the authors

V. D. Makhaev

Institute of Problems of Chemical Physics

Author for correspondence.
Email: vim@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast

L. A. Petrova

Institute of Problems of Chemical Physics

Email: vim@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast

Yu. M. Shulga

Institute of Problems of Chemical Physics

Email: vim@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast


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