Email this article Polyfluoroalkyl Phosphates Bearing Propargyl Substituents
- Authors: Verkhoturova S.I.1, Nalibaeva A.M.2, Arbuzova S.N.1, Kazantseva T.I.1, Zinchenko S.1, Mikhailenko V.L.3, Chernysheva N.A.1, Bishimbaeva G.K.2, Gusarova N.K.1, Trofimov B.A.1
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Affiliations:
- A.E. Favorskii Institute of Chemistry
- D.V. Sokolsky Institute of Fuel
- Irkutsk State University
- Issue: Vol 89, No 4 (2019)
- Pages: 708-712
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222854
- DOI: https://doi.org/10.1134/S107036321904011X
- ID: 222854
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Abstract
Polyfluoroalkyl dichlorophosphates react easily with propargyl alcohol under mild conditions (22–62°С, 3 h, pyridine-toluene) to form previously unknown bis(2-propynyl) polyfluoroalkyl phosphates with a yield of 36–41%, a triple bond in which is capable of participating in the azide-alkyne cycloaddition reaction.
About the authors
S. I. Verkhoturova
A.E. Favorskii Institute of Chemistry
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
A. M. Nalibaeva
D.V. Sokolsky Institute of Fuel
Email: boris_trofimov@irioch.irk.ru
Kazakhstan, Almaty
S. N. Arbuzova
A.E. Favorskii Institute of Chemistry
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
T. I. Kazantseva
A.E. Favorskii Institute of Chemistry
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
S.V. Zinchenko
A.E. Favorskii Institute of Chemistry
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
V. L. Mikhailenko
Irkutsk State University
Email: boris_trofimov@irioch.irk.ru
Russian Federation, Irkutsk
N. A. Chernysheva
A.E. Favorskii Institute of Chemistry
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
G. K. Bishimbaeva
D.V. Sokolsky Institute of Fuel
Email: boris_trofimov@irioch.irk.ru
Kazakhstan, Almaty
N. K. Gusarova
A.E. Favorskii Institute of Chemistry
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
B. A. Trofimov
A.E. Favorskii Institute of Chemistry
Author for correspondence.
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
