Synthesis, Spectral, and Coordination Properties of Halogen-Substituted Tetraarylporphyrins
- Authors: Ivanova Y.B.1, Chizhova N.V.1, Khrushkova Y.V.2, Rusanov A.I.2, Mamardashvili N.Z.1
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Affiliations:
- G.A. Krestov Institute of Solutions Chemistry of the Russian Academy of Sciences
- Ivanovo State University of Chemical Technology
- Issue: Vol 89, No 3 (2019)
- Pages: 459-465
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222791
- DOI: https://doi.org/10.1134/S1070363219030150
- ID: 222791
Cite item
Abstract
2,3,7,8,12,13,17,18-Ocatbromo-5,10,15,20-tetra-(4-chloroprienyl)porphyrin and 2,3,7,8,12,13,17,18-octachloro-5,10,15,20-tetra-(4-bromophenyl)porphyrin have been synthesized. The obtained compounds have been identified by electronic absorption and 1H NMR spectroscopy as well as mass spectrometry. The complex-forming properties of the synthesized porphyrins in the zinc acetate (II)-acetonitrile system at 278–298 K have been studied. Kinetic parameters of the formation of the corresponding zinc complexes in acetonitrile have been determined.
About the authors
Yu. B. Ivanova
G.A. Krestov Institute of Solutions Chemistry of the Russian Academy of Sciences
Author for correspondence.
Email: jjiv@yandex.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045
N. V. Chizhova
G.A. Krestov Institute of Solutions Chemistry of the Russian Academy of Sciences
Email: jjiv@yandex.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045
Yu. V. Khrushkova
Ivanovo State University of Chemical Technology
Email: jjiv@yandex.ru
Russian Federation, Ivanovo
A. I. Rusanov
Ivanovo State University of Chemical Technology
Email: jjiv@yandex.ru
Russian Federation, Ivanovo
N. Zh. Mamardashvili
G.A. Krestov Institute of Solutions Chemistry of the Russian Academy of Sciences
Email: jjiv@yandex.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045