Effect of Nitrogen-Containing Bases on Oxidation of Ferrocenylboric and Ferrocenylcarboxylic Acids with Hydrogen Peroxide in Water and Water–Acetonitrile Mixed Solvent
- Authors: Fomin V.M.1, Galkina M.S.1, Kochetkova K.S.1
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Affiliations:
- Lobachevsky State University of Nizhny Novgorod
- Issue: Vol 88, No 12 (2018)
- Pages: 2534-2539
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222588
- DOI: https://doi.org/10.1134/S1070363218120137
- ID: 222588
Cite item
Abstract
The effect of triethylamine and pyridine on the kinetics and mechanism of ferrocenylboric and ferrocenylcarboxylic acids oxidation with hydrogen peroxide in water and aqueous-organic media has been studied. The addition of amines has accelerated the oxidation of ferrocenylboric acid both by hydrogen peroxide and by oxygen. Triethylamine has slowed down the oxidation of ferrocenylacetic acid and stabilized the formed zwitter-ion Fc+CH2COO–. Ferrocenylcarboxylic acid has not been oxidized by H2O2. The mechanism of the reaction has been suggested.
About the authors
V. M. Fomin
Lobachevsky State University of Nizhny Novgorod
Author for correspondence.
Email: niih325@bk.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950
M. S. Galkina
Lobachevsky State University of Nizhny Novgorod
Email: niih325@bk.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950
K. S. Kochetkova
Lobachevsky State University of Nizhny Novgorod
Email: niih325@bk.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950
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