Generation of tert-Butyl-λ5-phosphanedione and Its Chemical Properties
- Authors: Kolodyazhnyi O.I.1, Grishkun E.V.1, Kolodyazhnaya A.O.1, Kolodyazhna O.O.1, Sheiko S.Y.1
-
Affiliations:
- Institute of Bioorganic and Petroleum Chemistry
- Issue: Vol 88, No 5 (2018)
- Pages: 919-924
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222182
- DOI: https://doi.org/10.1134/S1070363218050134
- ID: 222182
Cite item
Abstract
Flash vacuum thermolysis of trimethylsilyl tert-butylphosphonohalidates involved elimination of halo(trimethyl)silane with the formation of tert-butyl-λ5-phosphanedione whose structure was confirmed by chemical reactions. tert-Butyl-λ5-phosphanedione readily undergoes trimerization, reacts with 2-phenyloxirane to give cycloaddition product, and takes up alcohols.
About the authors
O. I. Kolodyazhnyi
Institute of Bioorganic and Petroleum Chemistry
Author for correspondence.
Email: olegkol321@gmail.com
Ukraine, ul. Murmanskaya 1, Kiev, 02094
E. V. Grishkun
Institute of Bioorganic and Petroleum Chemistry
Email: olegkol321@gmail.com
Ukraine, ul. Murmanskaya 1, Kiev, 02094
A. O. Kolodyazhnaya
Institute of Bioorganic and Petroleum Chemistry
Email: olegkol321@gmail.com
Ukraine, ul. Murmanskaya 1, Kiev, 02094
O. O. Kolodyazhna
Institute of Bioorganic and Petroleum Chemistry
Email: olegkol321@gmail.com
Ukraine, ul. Murmanskaya 1, Kiev, 02094
S. Yu. Sheiko
Institute of Bioorganic and Petroleum Chemistry
Email: olegkol321@gmail.com
Ukraine, ul. Murmanskaya 1, Kiev, 02094