Solubility of d-Element Salts in Organic and Aqueous–Organic Solvents: VI.1 Structure and Thermal Stability of Cadmium Iodide and Bromide Solvates with Dimethylacetamide and Dimethylformamide
- Authors: Bogachev N.A.1, Starova G.L.1, Razzhivin A.V.1, Skripkin M.Y.1, Nikolskii A.B.1
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Affiliations:
- St. Petersburg State University
- Issue: Vol 88, No 1 (2018)
- Pages: 1-6
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221930
- DOI: https://doi.org/10.1134/S1070363218010012
- ID: 221930
Cite item
Abstract
Five solvates, [CdBr2(DMF)]n, [CdBr2(DMA)]n, [CdI2(DMF)]n, [Cd(DMF)6][Cd2I6], and {[Cd(DMA)6][Cd5I12]n}m, were isolated from the ternary systems CdX2–L–H2O (X = Br, I; L = N,N-dimethylacetamide, N,N-dimethylformamide) and characterized by the X-ray single crystal analysis. The structures of the first three solvates is similar to each other in structures and represent a one-dimensional polymer chain, the fourth solvate has the discrete structure containing [Cd(DMF)6]2+ and [Cd2I6]2– ions, and the fifth solvate contains discrete [Cd(DMA)6]2+ cations and the polymer anionic fragment [Cd5I12]n2n–.
About the authors
N. A. Bogachev
St. Petersburg State University
Author for correspondence.
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
G. L. Starova
St. Petersburg State University
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. V. Razzhivin
St. Petersburg State University
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
M. Yu. Skripkin
St. Petersburg State University
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. B. Nikolskii
St. Petersburg State University
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
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