Solubility of d-Element Salts in Organic and Aqueous–Organic Solvents: VI.1 Structure and Thermal Stability of Cadmium Iodide and Bromide Solvates with Dimethylacetamide and Dimethylformamide

详细

Five solvates, [CdBr₂(DMF)]_n, [CdBr₂(DMA)]_n, [CdI²(DMF)]ⁿ, [Cd(DMF)₆][Cd₂I₆], and {[Cd(DMA)₆][Cd₅I₁₂]_n}_m, were isolated from the ternary systems CdX₂–L–H₂O (X = Br, I; L = N,N-dimethylacetamide, N,N-dimethylformamide) and characterized by the X-ray single crystal analysis. The structures of the first three solvates is similar to each other in structures and represent a one-dimensional polymer chain, the fourth solvate has the discrete structure containing [Cd(DMF)₆]²⁺ and [Cd₂I₆]^2– ions, and the fifth solvate contains discrete [Cd(DMA)₆]²⁺ cations and the polymer anionic fragment [Cd₅I₁₂]_n^2n–.