Study of the Rheological Properties of Aqueous Solutions of Porphyrin Polymers
- Authors: Alopina E.V.1, Usacheva T.S.1, Ageeva T.A.1, Koifman O.I.1,2
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Affiliations:
- Ivanovo State University of Chemistry and Technology
- Krestov Institute of Solution Chemistry
- Issue: Vol 87, No 12 (2017)
- Pages: 3097-3101
- Section: Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
- URL: https://journals.rcsi.science/1070-3632/article/view/221874
- DOI: https://doi.org/10.1134/S1070363217120593
- ID: 221874
Cite item
Abstract
The behavior of porphyrin polymers derived from polyvinyl alcohol in aqueous solutions was investigated by viscometry. It was found that increasing amount of porphyrin in the immobilizate increases the size of the macromolecular coil of polyvinyl alcohol due to the incorporation of the tetrapyrrole macroheterocycle into the polymer matrix. It was shown that the immobilized porphyrin structure does not affect the nature of the polymer‒solvent interaction.
About the authors
E. V. Alopina
Ivanovo State University of Chemistry and Technology
Author for correspondence.
Email: alopina@mail.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000
T. S. Usacheva
Ivanovo State University of Chemistry and Technology
Email: alopina@mail.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000
T. A. Ageeva
Ivanovo State University of Chemistry and Technology
Email: alopina@mail.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000
O. I. Koifman
Ivanovo State University of Chemistry and Technology; Krestov Institute of Solution Chemistry
Email: alopina@mail.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000; Ivanovo