Light-induced formation of nitroxyl radicals by organic Bi(V) compounds in the presence of 2-methyl-2-nitrosopropane and C-phenyl-N-tert-butylnitrone
- Authors: Gushchin A.V.1, Kalistratova O.S.1, Maleeva A.I.1, Dodonov V.A.1, Kosov D.Y.1, Emel’yanov D.N.1, Kuropatov V.A.2
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Affiliations:
- Lobachevskii Nizhny Novgorod State University
- Razuvaev Institute of Organometallic Chemistry
- Issue: Vol 87, No 7 (2017)
- Pages: 1547-1549
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220728
- DOI: https://doi.org/10.1134/S1070363217070179
- ID: 220728
Cite item
Abstract
The organic bismuth compounds Ph3Bi(O2CCH=CHCH3)2 and Ph3Bi(O2CEt)2 decompose under scattered light in the presence of spin traps (2-methyl-2-nitrosopropane and C-phenyl-N-tert-butylnitrone) in organic solvents (acetonitrile, benzene, toluene) to form adducts of phenyl radicals with the traps.
About the authors
A. V. Gushchin
Lobachevskii Nizhny Novgorod State University
Author for correspondence.
Email: gushchin4@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod
O. S. Kalistratova
Lobachevskii Nizhny Novgorod State University
Email: gushchin4@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod
A. I. Maleeva
Lobachevskii Nizhny Novgorod State University
Email: gushchin4@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod
V. A. Dodonov
Lobachevskii Nizhny Novgorod State University
Email: gushchin4@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod
D. Yu. Kosov
Lobachevskii Nizhny Novgorod State University
Email: gushchin4@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod
D. N. Emel’yanov
Lobachevskii Nizhny Novgorod State University
Email: gushchin4@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod
V. A. Kuropatov
Razuvaev Institute of Organometallic Chemistry
Email: gushchin4@yandex.ru
Russian Federation, Nizhny Novgorod