Luminescence and photochemical properties of hydrazones of aromatic aldehydes


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Abstract

Luminescence and photochemical properties found by us earlier for several hydrazones of aromatic aldehydes have been shown to be characteristic also of other compounds of this class. The structure of the product of reversible photochemical reaction of hydrazones of aromatic aldehydes is explained by specific interactions between the lone electron pairs of the two vicinal nitrogen atoms in the molecule of hydrazine. Compounds possessing photochromic properties have been suggested and prerequisites of application of luminescent hydrazones as luminophors have been formulated.

About the authors

L. D. Popov

Southern Federal University

Author for correspondence.
Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090

V. S. Orekhovskii

Technion – Israel Institute of Technology

Email: ldpopov@mail.ru
Israel, Technion City, Haifa, 32000

Yu. V. Revinskii

Southern Scientific Center of Russian Academy of Sciences

Email: ldpopov@mail.ru
Russian Federation, Rostov-on-Don

E. N. Shepelenko

Southern Scientific Center of Russian Academy of Sciences

Email: ldpopov@mail.ru
Russian Federation, Rostov-on-Don

S. A. Borodkin

Southern Federal University

Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090

I. V. Koretskii

Southern Federal University

Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090


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