Luminescence and photochemical properties of hydrazones of aromatic aldehydes
- Authors: Popov L.D.1, Orekhovskii V.S.2, Revinskii Y.V.3, Shepelenko E.N.3, Borodkin S.A.1, Koretskii I.V.1
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Affiliations:
- Southern Federal University
- Technion – Israel Institute of Technology
- Southern Scientific Center of Russian Academy of Sciences
- Issue: Vol 87, No 5 (2017)
- Pages: 945-951
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/219690
- DOI: https://doi.org/10.1134/S1070363217050097
- ID: 219690
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Abstract
Luminescence and photochemical properties found by us earlier for several hydrazones of aromatic aldehydes have been shown to be characteristic also of other compounds of this class. The structure of the product of reversible photochemical reaction of hydrazones of aromatic aldehydes is explained by specific interactions between the lone electron pairs of the two vicinal nitrogen atoms in the molecule of hydrazine. Compounds possessing photochromic properties have been suggested and prerequisites of application of luminescent hydrazones as luminophors have been formulated.
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About the authors
L. D. Popov
Southern Federal University
Author for correspondence.
Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090
V. S. Orekhovskii
Technion – Israel Institute of Technology
Email: ldpopov@mail.ru
Israel, Technion City, Haifa, 32000
Yu. V. Revinskii
Southern Scientific Center of Russian Academy of Sciences
Email: ldpopov@mail.ru
Russian Federation, Rostov-on-Don
E. N. Shepelenko
Southern Scientific Center of Russian Academy of Sciences
Email: ldpopov@mail.ru
Russian Federation, Rostov-on-Don
S. A. Borodkin
Southern Federal University
Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090
I. V. Koretskii
Southern Federal University
Email: ldpopov@mail.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344090