Mechanism of dehydrochlorination of 2,2-diaryl-1,1,1-trichloroethanes with nitrite and halide anions
- Authors: Kazin V.N.1, Kuzhin M.B.1, Sibrikov S.G.1, Sirik A.V.1, Guzov E.A.1, Plakhtinskii V.V.1
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Affiliations:
- Demidov Yaroslavl State University
- Issue: Vol 87, No 3 (2017)
- Pages: 381-385
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/218617
- DOI: https://doi.org/10.1134/S1070363217030033
- ID: 218617
Cite item
Abstract
The reactivity of 2,2-diphenyl-1,1,1-trichloroethane toward halide ions in dipolar aprotic solvents has been studied, and the mechanisms of its reactions with nitrite and halide ions have been compared. The results of kinetic and DFT quantum chemical studies suggest a common bimolecular elimination mechanism for both dehydrochlorination reactions.
About the authors
V. N. Kazin
Demidov Yaroslavl State University
Author for correspondence.
Email: kaz@bio.uniyar.ac.ru
Russian Federation, ul. Sovetskaya 14, Yaroslavl, 150003
M. B. Kuzhin
Demidov Yaroslavl State University
Email: kaz@bio.uniyar.ac.ru
Russian Federation, ul. Sovetskaya 14, Yaroslavl, 150003
S. G. Sibrikov
Demidov Yaroslavl State University
Email: kaz@bio.uniyar.ac.ru
Russian Federation, ul. Sovetskaya 14, Yaroslavl, 150003
A. V. Sirik
Demidov Yaroslavl State University
Email: kaz@bio.uniyar.ac.ru
Russian Federation, ul. Sovetskaya 14, Yaroslavl, 150003
E. A. Guzov
Demidov Yaroslavl State University
Email: kaz@bio.uniyar.ac.ru
Russian Federation, ul. Sovetskaya 14, Yaroslavl, 150003
V. V. Plakhtinskii
Demidov Yaroslavl State University
Email: kaz@bio.uniyar.ac.ru
Russian Federation, ul. Sovetskaya 14, Yaroslavl, 150003