Promoting non-transition metal alkylation with organic halides in the presence of binary systems based on an organometallic compound and a transition metal compound: IX. Alkylation of aluminum and concluding remarks
- Authors: Eremeev I.V.1
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Affiliations:
- Alekseev Nizhny Novgorod State Technical University
- Issue: Vol 86, No 7 (2016)
- Pages: 1563-1566
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215633
- DOI: https://doi.org/10.1134/S1070363216070057
- ID: 215633
Cite item
Abstract
Study of aluminum powder alkylation with ethyl bromide in the presence of ethylaluminum sesquibromide and copper(I) iodide has revealed that binary systems based on an organometallic compound and a transition metal compound are efficient promotors of direct synthesis of organoaluminum compounds as well. Major conclusions drawn in a series of studies on non-transition metals (Zn, Cd, and Al) alkylation with organic halides in the presence of the binary systems are summarized.
Keywords
About the authors
I. V. Eremeev
Alekseev Nizhny Novgorod State Technical University
Author for correspondence.
Email: igor.eremeev@rambler.ru
Russian Federation, ul. Minina 24, Nizhny Novgorod, 603950