Synthesis of azidooxetane statistical polymers and copolymers
- Authors: Garaev I.K.1, Kostochko A.V.1, Petrov A.I.1, Ibragimov E.N.2, Golubev A.E.2
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Affiliations:
- Kazan National Research Technical University
- Research Institute of Polymer Materials
- Issue: Vol 86, No 6 (2016)
- Pages: 1459-1468
- Section: Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
- URL: https://journals.rcsi.science/1070-3632/article/view/215514
- DOI: https://doi.org/10.1134/S1070363216060384
- ID: 215514
Cite item
Abstract
Statistical polymers and copolymers were firstly synthesized by polymerization of 3,3-bis(azidomethyl) oxetane (BAMO) and 3-azidomethyl-3-methyloxetane (AMMO) in a triisobutylaluminum–water catalytic system, and their physicochemical, physicomechanical, and themochemical properties were studied. It was found that with increasing fraction of poly-AMMO in the BAMO/AMMO copolymers the strength properties of the copolymers enhance and the degree of crystallinity decreases.
About the authors
I. Kh. Garaev
Kazan National Research Technical University
Author for correspondence.
Email: nppdiol@mail.ru
Russian Federation, p/b 48, Kazan, Tatarstan, 420139
A. V. Kostochko
Kazan National Research Technical University
Email: nppdiol@mail.ru
Russian Federation, p/b 48, Kazan, Tatarstan, 420139
A. I. Petrov
Kazan National Research Technical University
Email: nppdiol@mail.ru
Russian Federation, p/b 48, Kazan, Tatarstan, 420139
E. N. Ibragimov
Research Institute of Polymer Materials
Email: nppdiol@mail.ru
Russian Federation, ul. Chistopol’skaya 16, Perm, 614101
A. E. Golubev
Research Institute of Polymer Materials
Email: nppdiol@mail.ru
Russian Federation, ul. Chistopol’skaya 16, Perm, 614101