Synthesis of azidooxetane statistical polymers and copolymers

I. Kh. Garaev; A. V. Kostochko; A. I. Petrov; E. N. Ibragimov; A. E. Golubev

doi:10.1134/S1070363216060384

Synthesis of azidooxetane statistical polymers and copolymers

Authors: Garaev I.K.¹, Kostochko A.V.¹, Petrov A.I.¹, Ibragimov E.N.², Golubev A.E.²
Affiliations:
1. Kazan National Research Technical University
2. Research Institute of Polymer Materials
Issue: Vol 86, No 6 (2016)
Pages: 1459-1468
Section: Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
URL: https://journals.rcsi.science/1070-3632/article/view/215514
DOI: https://doi.org/10.1134/S1070363216060384
ID: 215514

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Abstract
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Abstract

Statistical polymers and copolymers were firstly synthesized by polymerization of 3,3-bis(azidomethyl) oxetane (BAMO) and 3-azidomethyl-3-methyloxetane (AMMO) in a triisobutylaluminum–water catalytic system, and their physicochemical, physicomechanical, and themochemical properties were studied. It was found that with increasing fraction of poly-AMMO in the BAMO/AMMO copolymers the strength properties of the copolymers enhance and the degree of crystallinity decreases.