Email this article Effect of the cation structure on the thermal stability of ionic liquids, quaternary ammonium tetrachloroferrates(III)
- Authors: Voronchikhina L.I.1, Zhuravlev O.E.1, Verolainen N.V.1, Krotova N.I.1
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Affiliations:
- Tver State University
- Issue: Vol 86, No 6 (2016)
- Pages: 1314-1318
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215276
- DOI: https://doi.org/10.1134/S1070363216060153
- ID: 215276
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Abstract
New ionic liquids, tetrachloroferrates(III) of quaternary ammonium salts [(CH3)2NR1R2]FeCl4 [R1 = CH3; C4H9; (CH2)3CN. R2 = C10H21; C16H33; CH2CH2OH; CH2C6H5], were synthesized and their thermal stability was investigated in air in the range 25–600°С. The mechanism of thermal decomposition of the investigated ionic liquids is suggested in agreement with Hofmann’s rule as β-E2-elimination.
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About the authors
L. I. Voronchikhina
Tver State University
Author for correspondence.
Email: pifchem@mail.ru
Russian Federation, Sadovyi per. 35, Tver, 170002
O. E. Zhuravlev
Tver State University
Email: pifchem@mail.ru
Russian Federation, Sadovyi per. 35, Tver, 170002
N. V. Verolainen
Tver State University
Email: pifchem@mail.ru
Russian Federation, Sadovyi per. 35, Tver, 170002
N. I. Krotova
Tver State University
Email: pifchem@mail.ru
Russian Federation, Sadovyi per. 35, Tver, 170002
