Synthesis and properties of bromine-substituted Co(II) tetraphenylporphyrinates
- Authors: Chizhova N.V.1, Zvezdina S.V.1, Mamardashvili N.Z.1
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Affiliations:
- Krestov Institute of Solutions Chemistry
- Issue: Vol 86, No 5 (2016)
- Pages: 1091-1094
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/214976
- DOI: https://doi.org/10.1134/S1070363216050182
- ID: 214976
Cite item
Abstract
The interaction of bromine-substituted tetraphenylporphyrins with cobalt(II) acetate in a chloroform–methanol mixture yielding the corresponding cobalt(II) porphyrinates has been studied by means of spectrophotometry. Treatment of Co(II) porphyrinates with bromine in the same medium has afforded the Co(III) porphyrinates.
About the authors
N. V. Chizhova
Krestov Institute of Solutions Chemistry
Author for correspondence.
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045
S. V. Zvezdina
Krestov Institute of Solutions Chemistry
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045
N. Zh. Mamardashvili
Krestov Institute of Solutions Chemistry
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045