Synthesis and properties of bromine-substituted Co(II) tetraphenylporphyrinates


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Abstract

The interaction of bromine-substituted tetraphenylporphyrins with cobalt(II) acetate in a chloroform–methanol mixture yielding the corresponding cobalt(II) porphyrinates has been studied by means of spectrophotometry. Treatment of Co(II) porphyrinates with bromine in the same medium has afforded the Co(III) porphyrinates.

About the authors

N. V. Chizhova

Krestov Institute of Solutions Chemistry

Author for correspondence.
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045

S. V. Zvezdina

Krestov Institute of Solutions Chemistry

Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045

N. Zh. Mamardashvili

Krestov Institute of Solutions Chemistry

Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045


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