2-Ethoxy-2,3-dihydro[d][1,2]oxaphosphole 2-oxide in the synthesis of dialkyl(diaryl)(2-hydroxybenzyl)phosphine oxides


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Abstract

A facile method of synthesis of functionally substituted P(IV) derivatives―dialkyl(diaryl)(2-hydroxybenzyl) phosphine oxides―by the reaction of 2-ethoxy-2,3-dihydro[d][1,2]oxaphosphole 2-oxide with organomagnesium compounds, which allows wide variation of substituents on the phosphorus atom was developed.

About the authors

D. A. Tatarinov

Arbuzov Institute of Organic and Physical Chemistry

Author for correspondence.
Email: datint@iopc.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

D. M. Kuznetsov

Arbuzov Institute of Organic and Physical Chemistry

Email: datint@iopc.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

A. A. Kostin

Arbuzov Institute of Organic and Physical Chemistry

Email: datint@iopc.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

V. F. Mironov

Arbuzov Institute of Organic and Physical Chemistry

Email: datint@iopc.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088


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