Iridium-catalyzed cascade dehydrogenation, ring-closure reaction leading to 2,4,6-triaryl-1,3,5-triazines


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Abstract

An efficient iridium-catalyzed dehydrogenation, ring-closure reaction, has been developed via a cascade sequence, in which [Cp*IrI2]2/Xantphos proved to be the most efficient catalyst for the synthesis of 2,4,6-triaryl-1,3,5-triazines from stable aryl-substituted alcohols and amidines. It was the first case of iridium catalyst successful application in such transformation.

About the authors

Gang Shi

The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering

Email: liying@jiangnan.edu.cn
China, Wuxi, Jiangsu Province, 214122

Fei He

The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering

Email: liying@jiangnan.edu.cn
China, Wuxi, Jiangsu Province, 214122

Youxin Che

The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering

Email: liying@jiangnan.edu.cn
China, Wuxi, Jiangsu Province, 214122

Caihua Ni

The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering

Email: liying@jiangnan.edu.cn
China, Wuxi, Jiangsu Province, 214122

Ying Li

The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering; National Engineering Laboratory for Cereal Fermentation Technology

Author for correspondence.
Email: liying@jiangnan.edu.cn
China, Wuxi, Jiangsu Province, 214122; Wuxi, Jiangsu Province, 214122


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