Iridium-catalyzed cascade dehydrogenation, ring-closure reaction leading to 2,4,6-triaryl-1,3,5-triazines
- Authors: Shi G.1, He F.1, Che Y.1, Ni C.1, Li Y.1,2
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Affiliations:
- The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering
- National Engineering Laboratory for Cereal Fermentation Technology
- Issue: Vol 86, No 2 (2016)
- Pages: 380-386
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213948
- DOI: https://doi.org/10.1134/S1070363216020304
- ID: 213948
Cite item
Abstract
An efficient iridium-catalyzed dehydrogenation, ring-closure reaction, has been developed via a cascade sequence, in which [Cp*IrI2]2/Xantphos proved to be the most efficient catalyst for the synthesis of 2,4,6-triaryl-1,3,5-triazines from stable aryl-substituted alcohols and amidines. It was the first case of iridium catalyst successful application in such transformation.
About the authors
Gang Shi
The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering
Email: liying@jiangnan.edu.cn
China, Wuxi, Jiangsu Province, 214122
Fei He
The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering
Email: liying@jiangnan.edu.cn
China, Wuxi, Jiangsu Province, 214122
Youxin Che
The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering
Email: liying@jiangnan.edu.cn
China, Wuxi, Jiangsu Province, 214122
Caihua Ni
The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering
Email: liying@jiangnan.edu.cn
China, Wuxi, Jiangsu Province, 214122
Ying Li
The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering; National Engineering Laboratory for Cereal Fermentation Technology
Author for correspondence.
Email: liying@jiangnan.edu.cn
China, Wuxi, Jiangsu Province, 214122; Wuxi, Jiangsu Province, 214122