Efficient Synthesis of Phenoxathiines via the Cascade C–H Hydroxylation–C–S Coupling–C–O Cyclization Reaction


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Abstract

The ligand-free and simple cascade C–H hydroxylation–C–S coupling–C–O cyclization reaction has been used as the synthetic approach to disulfides and o-chloro-iodobenzenes using CuI as a catalyst. This approach provides an easy and convenient method of synthesis of phenoxathiin derivatives.

About the authors

Fei Chao

Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, College of Materials and Chemical Engineering

Email: wanglongchem@ctgu.edu.cn
China, Yichang, Hubei, 443002

Wen-Heng Xu

Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, College of Materials and Chemical Engineering

Email: wanglongchem@ctgu.edu.cn
China, Yichang, Hubei, 443002

Zhi-Lin Ren

College of Chemical Engineering

Email: wanglongchem@ctgu.edu.cn
China, Xiangyang, Hubei, 441053

Long Wang

Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, College of Materials and Chemical Engineering; Material Analysis and Testing Center

Author for correspondence.
Email: wanglongchem@ctgu.edu.cn
China, Yichang, Hubei, 443002; Yichang, Hubei, 443002


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