Reactions of Benzylidene Chlorides with  S -Methyl Diethylphosphinothioate

M. B. Gazizov; G. D. Valieva; S. Yu. Ivanova; R. F. Karimova; R. A. Khairullin; K. S. Gazizova

doi:10.1134/S1070363219120107

Reactions of Benzylidene Chlorides with S-Methyl Diethylphosphinothioate

Authors: Gazizov M.B.¹, Valieva G.D.¹, Ivanova S.Y.¹, Karimova R.F.¹, Khairullin R.A.¹, Gazizova K.S.¹
Affiliations:
1. Kazan National Research Technological University
Issue: Vol 89, No 12 (2019)
Pages: 2386-2389
Section: Article
URL: https://journals.rcsi.science/1070-3632/article/view/223194
DOI: https://doi.org/10.1134/S1070363219120107
ID: 223194

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Abstract

S-Methyl diethylphosphinothioate reacted with benzylidene chlorides to give the corresponding aryl(chloro)methyl methyl sulfide and diethylphosphinoyl chloride. The product structure suggests initial attack of the methylsulfanyl group on the CH carbon atom of dichloromethylarene. Arenecarbothialdehyde dithioacetals and trimers and O,O-dialkyl[aryl(methylsulfanyl)methyl]phosphonates were synthesized.