Tri-n-butylphosphine-Catalyzed Phosphonoethylation Reactions of Hydrophosphoryl Compounds


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Abstract

An efficient method for the synthesis of 1,2-bisphosphoryl compounds based on the addition of hydrophosphoryl derivatives to O,O-diethyl vinylphosphonate was developed. The reaction proceeds in mild conditions under catalysis with tri-n-butylphosphine and leads to the formation of the corresponding target products with high yield.

About the authors

A. V. Il’in

Kazan (Volga Region) Federal University

Author for correspondence.
Email: antonilin.1989@mail.ru
Russian Federation, Kazan, 420008

A. A. Antonova

Kazan (Volga Region) Federal University

Email: antonilin.1989@mail.ru
Russian Federation, Kazan, 420008

N. G. Khusainova

Kazan (Volga Region) Federal University

Email: antonilin.1989@mail.ru
Russian Federation, Kazan, 420008

V. I. Galkin

Kazan (Volga Region) Federal University

Email: antonilin.1989@mail.ru
Russian Federation, Kazan, 420008


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