Manganese and Iron Complexes with Malonic Acid Bis[2-(3,5-di-tert-butyl-2-hydroxybenzyl)hydrazide]


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Abstract

New manganese(II) and iron(III) complexes with hydrazones derived from malonic acid dihydrazide and 3,5-di-tert-butylsalicylaldehyde have been synthesized. The structure of the complexes has been studied by IR and electronic spectroscopy and X-ray analysis. Malonic acid bis[(2-hydroxy-3,5-di-tert-butylbenzylidene)-hydrazide] has been shown to form dinuclear complexes with manganese and iron ions, in which ferromagnetic interaction between the metal ions is observed.

About the authors

P. A. Fatullaeva

Nagiev Institute of Catalysis and Inorganic Chemistry

Author for correspondence.
Email: iradam@rambler.ru
Azerbaijan, Baku


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