A Solution-Solid Phase Equilibrium in Ternary Systems Containing d-Elements Salts and Mixed Oxygen-Donor Solvent


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Abstract

The results of the study of ternary systems containing copper, cobalt, nickel, and cadmium halides and sulfates in binary water-organic and mixed organic solvents are summarized. The influence of the donor-acceptor properties of the ternary system components, the relative dielectric permittivity, and the intermolecular association in the mixed solvent on the solubility of salts and the crystalline structure of solvates is analyzed.

About the authors

N. A. Bogachev

St. Petersburg State University

Author for correspondence.
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7-9, St. Petersburg, 199034

A. O. Gorbunov

St. Petersburg State University

Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7-9, St. Petersburg, 199034

M. Yu. Skripkin

St. Petersburg State University

Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7-9, St. Petersburg, 199034

A. B. Nikol’skii

St. Petersburg State University

Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7-9, St. Petersburg, 199034


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