Solubility of d-Element Salts in Organic and Aqueous-Organic Solvents: VII. Structure of Nickel Chloride Solvatocomplexes
- Authors: Bogachev N.A.1, Tsyrul’nikov N.A.1, Makarova A.A.1, Tolmachev M.V.1, Starova G.L.1, Skripkin M.Y.1, Nikol’skii A.B.1
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Affiliations:
- St. Petersburg State University
- Issue: Vol 89, No 5 (2019)
- Pages: 859-864
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222890
- DOI: https://doi.org/10.1134/S1070363219050013
- ID: 222890
Cite item
Abstract
Four complexes [Ni(DMA)2(H2O)4]Cl2·2H2O, [Ni(DMF)2(H2O)4]Cl2·2H2O, and [Ni(DMA)6][NiCl4], [Ni(DMF)2(H2O)2Cl2] were isolated from ternary water-organic saline systems containing nickel chloride and N, N-dimethylacetamide-water and N, N-dimethylformamide-water binary solvents. The obtained complexes were studied by X-ray structural analysis. The formation of hydrogen bonds between water molecules of the nickel ion solvate sphere, chloride ions, and non-coordinated water molecules located in the cavity of the crystal structure was detected.
About the authors
N. A. Bogachev
St. Petersburg State University
Author for correspondence.
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
N. A. Tsyrul’nikov
St. Petersburg State University
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. A. Makarova
St. Petersburg State University
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
M. V. Tolmachev
St. Petersburg State University
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
G. L. Starova
St. Petersburg State University
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
M. Yu. Skripkin
St. Petersburg State University
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. B. Nikol’skii
St. Petersburg State University
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
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