Email this article Hydroxylation of Polychlorinated Biphenyls in Polyalkanolamines Medium
- Authors: Gorbunova T.I.1, Pervova M.G.1, Saloutin V.I.1, Chupakhin O.N.1
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Affiliations:
- I.Ya. Postovskii Institute of Organic Synthesis, Ural Branch
- Issue: Vol 89, No 4 (2019)
- Pages: 717-721
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222857
- DOI: https://doi.org/10.1134/S1070363219040133
- ID: 222857
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Abstract
The reaction of congeners of polychlorinated biphenyls with potassium hydroxide has been studied using different polyalkanolamines as the solvent. Predominant formation of hydroxy derivatives under the conditions of thermodynamic control has been observed. The conversion of the congeners of polychlorinated biphenyls in the hydroxylation reaction and the number of the introduced hydroxy groups depends on the basicity of the polyalkanolamine.
About the authors
T. I. Gorbunova
I.Ya. Postovskii Institute of Organic Synthesis, Ural Branch
Author for correspondence.
Email: gorbunova@ios.uran.ru
Russian Federation, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
M. G. Pervova
I.Ya. Postovskii Institute of Organic Synthesis, Ural Branch
Email: gorbunova@ios.uran.ru
Russian Federation, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
V. I. Saloutin
I.Ya. Postovskii Institute of Organic Synthesis, Ural Branch
Email: gorbunova@ios.uran.ru
Russian Federation, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
O. N. Chupakhin
I.Ya. Postovskii Institute of Organic Synthesis, Ural Branch
Email: gorbunova@ios.uran.ru
Russian Federation, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
