Alkyl 3-Bromo-3-nitroacrylates in Reactions with Aliphatic Alcohols


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Abstract

The reactions of alkyl 3-bromo-3-nitroacrylates with aliphatic alcohols at reflux led to the formation of O-adducts—alkyl 2-alkoxy-3-bromo-3-nitropropanoates isolated as mixtures of diastereomers; their structure was proved using 1H, 13C-{1H} NMR, and IR spectroscopy methods.

About the authors

S. V. Makarenko

Herzen State Pedagogical

Author for correspondence.
Email: kohrgpu@yandex.ru
Russian Federation, nab. r. Moiki 48, St. Petersburg, 191186

V. V. Pelipko

Herzen State Pedagogical

Email: kohrgpu@yandex.ru
Russian Federation, nab. r. Moiki 48, St. Petersburg, 191186

M. M. Pavchenko

Herzen State Pedagogical

Email: kohrgpu@yandex.ru
Russian Federation, nab. r. Moiki 48, St. Petersburg, 191186

R. I. Baichurin

Herzen State Pedagogical

Email: kohrgpu@yandex.ru
Russian Federation, nab. r. Moiki 48, St. Petersburg, 191186


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