Synthesis, Photo-, and Ionochromic Properties of Indolyl(thienyl)maleimides with Terpyridine Receptor
- Authors: Shepelenko E.N.1, Podshibyakin V.A.2, Tikhomirova K.S.2, Dubonosov A.D.1, Bren’ V.A.2, Minkin V.I.1,2
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Affiliations:
- Federal Research Centre the Southern Scientific Centre of the Russian Academy of Sciences
- Institute of Physical and Organic Chemistry
- Issue: Vol 89, No 3 (2019)
- Pages: 409-415
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222781
- DOI: https://doi.org/10.1134/S1070363219030071
- ID: 222781
Cite item
Abstract
Indolyl(thienyl)maleimides with terpyridine receptor in the bridge part have been synthesized. Irradiation of their toluene solutions with light at λ = 436 nm has led to the formation of cyclic isomers. The reverse ring opening reaction has occurred during the photolysis with visible light (λ > 500 nm). 1-(4-([2,2′:6′,2″-Terpyridin]-4′-yl)phenyl)derivatives have exhibited the properties of chromogenic naked-eye sensors to Fe2+ cations in acetonitrile solution, changing the solution color from bright-orange to red.
About the authors
E. N. Shepelenko
Federal Research Centre the Southern Scientific Centre of the Russian Academy of Sciences
Email: aled@ipoc.sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
V. A. Podshibyakin
Institute of Physical and Organic Chemistry
Email: aled@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don
K. S. Tikhomirova
Institute of Physical and Organic Chemistry
Email: aled@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don
A. D. Dubonosov
Federal Research Centre the Southern Scientific Centre of the Russian Academy of Sciences
Author for correspondence.
Email: aled@ipoc.sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
V. A. Bren’
Institute of Physical and Organic Chemistry
Email: aled@ipoc.sfedu.ru
Russian Federation, Rostov-on-Don
V. I. Minkin
Federal Research Centre the Southern Scientific Centre of the Russian Academy of Sciences; Institute of Physical and Organic Chemistry
Email: aled@ipoc.sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090; Rostov-on-Don