2,3,9,10,16,17,23,24-Octakis-[(4-phenoxy)phenoxy]phthalocyanine and Its Erbium Complexes. Synthesis, Spectral, and Luminescent Properties, Self-Association


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Abstract

4,5-bis[(4-phenoxy)phenoxy]phthalonitrile was obtained by the reaction of 4,5-dichlorophthalonitrile with 4-phenoxyphenol. On its basis 2,3,9,10,16,17,23,24-octakis-[(4-phenoxy)phenoxy]phthalocyanine and its single- and double-decked complexes with erbium were synthesized. Spectral-luminescent properties of resulting phthalocyanines were studied. The tendency of phthalocyanines to association in dichloromethane depends on the structure of their molecules.

About the authors

A. I. Koptyaev

Ivanovo State University of Chemistry and Technology

Email: nik-galanin@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 153000

N. E. Galanin

Ivanovo State University of Chemistry and Technology

Author for correspondence.
Email: nik-galanin@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 153000

G. P. Shaposhnikov

Ivanovo State University of Chemistry and Technology

Email: nik-galanin@yandex.ru
Russian Federation, pr. Sheremetevskii 7, Ivanovo, 153000


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