Email this article Zinc(II) Complexes with Tetrafluoroterephthalic and Octafluorobiphenyl-4,4′-dicarboxylic Acid Anions and 1,10-Phenanthroline
- Authors: Larionov S.V.1,2, Rakhmanova M.I.1, Glinskaya L.A.1, Naumov D.Y.1,2, Vinogradov A.S.3, Karpov V.M.3, Platonov V.E.3, Fadeeva V.P.2,3
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
- Issue: Vol 89, No 2 (2019)
- Pages: 261-265
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222751
- DOI: https://doi.org/10.1134/S1070363219020154
- ID: 222751
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Abstract
Zinc(II) complexes with 1,10-phenanthroline and tetrafluoroterephthalate and octafluorobiphenyl 4,4′-dicarboxylate anions have been synthesized. According to the IR spectral data, the complexation involves coordination of the metal ion to the nitrogen atoms of phenanthroline and carboxylate oxygen atom of the acid anion. The complexes show photoluminescence in the visible region of the spectrum. The structure of the complex salt [Zn(H2O)6][Zn(H2O)4(L2)2] · H2O, where L2 is octafluorobiphenyl-4,4′-dicarboxylate anion (monodentate ligand), has been determined by X-ray analysis.
About the authors
S. V. Larionov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: glinsk@niic.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 1, Novosibirsk, 630090
M. I. Rakhmanova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: glinsk@niic.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090
L. A. Glinskaya
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Author for correspondence.
Email: glinsk@niic.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090
D. Yu. Naumov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: glinsk@niic.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 1, Novosibirsk, 630090
A. S. Vinogradov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: glinsk@niic.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
V. M. Karpov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: glinsk@niic.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
V. E. Platonov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: glinsk@niic.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
V. P. Fadeeva
Novosibirsk National Research State University; Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: glinsk@niic.nsc.ru
Russian Federation, ul. Pirogova 1, Novosibirsk, 630090; pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
