Monolayers of Supramolecular Cryptate Complexes at the Electrode/Solution Interface


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Abstract

The results of investigation of the electrochemical properties of cryptand 222 from the macropolycyclic ligands group and its complexes with cations were summarized. Emphasis was placed on the properties of the adsorbed layers of these substances at the electrode/solution interface. Adsorption parameters of the compounds studied were calculated in the framework of the Frumkin–Damaskin theory of adsorption of organic substances using the regression analysis. Comparative analysis of the data obtained was carried out.

About the authors

E. V. Stenina

Lomonosov Moscow State University

Author for correspondence.
Email: estenina@yandex.ru
Russian Federation, Moscow, 119991

L. N. Sviridova

Lomonosov Moscow State University

Author for correspondence.
Email: slianan@mail.ru
Russian Federation, Moscow, 119991

V. F. Stenin

Interdepartmental Center for Analytical Research in Physics

Author for correspondence.
Email: valery8008@mail.ru
Russian Federation, Profsoyuznaya ul. 65, Moscow, 117342


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