Email this article Synthesis and Spectral Characteristics of Sn(IV) Tetraphenylporphyrinates
- Authors: Chizhova N.V.1, Shinkarenko A.V.2, Mamardashvili N.Z.1
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Affiliations:
- Krestov Institute of Solutions Chemistry
- Ivanovo State University of Chemistry and Technology
- Issue: Vol 88, No 12 (2018)
- Pages: 2559-2563
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222592
- DOI: https://doi.org/10.1134/S1070363218120162
- ID: 222592
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Abstract
Coordination reactions of 5,10,15,20-tetraphenylporphyrin, 2-bromo-5,10,15,20-tetraphenylporphyrin, 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin, 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrin and metal-exchange reactions of their cadmium complexes with tin(II) chloride in dimethylformamide are described. Optimum conditions for the synthesis of Sn(IV) tetraphenylporphyrinates have been elaborated. The obtained substances have been identified by electron absorption spectroscopy, 1H NMR spectroscopy, and mass-spectroscopy.
About the authors
N. V. Chizhova
Krestov Institute of Solutions Chemistry
Author for correspondence.
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045
A. V. Shinkarenko
Ivanovo State University of Chemistry and Technology
Email: nvc@isc-ras.ru
Russian Federation, Ivanovo
N. Zh. Mamardashvili
Krestov Institute of Solutions Chemistry
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045
