Synthesis of a 16-Membered P 4 N 2  Macrocycle with Pyridyl-Substituted Phosphorus Atoms

T. I. Wittmann; E. I. Musina; I. A. Litvinov; A. A. Karasik; O. G. Sinyashin

doi:10.1134/S1070363218110336

Synthesis of a 16-Membered P₄N₂ Macrocycle with Pyridyl-Substituted Phosphorus Atoms

Authors: Wittmann T.I.¹, Musina E.I.¹, Litvinov I.A.¹, Karasik A.A.¹, Sinyashin O.G.¹
Affiliations:
1. A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center
Issue: Vol 88, No 11 (2018)
Pages: 2449-2452
Section: Letters to the Editor
URL: https://journals.rcsi.science/1070-3632/article/view/222569
DOI: https://doi.org/10.1134/S1070363218110336
ID: 222569

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Abstract

The first example of 16-membered aminomethylphosphines with pyridyl substituents on the phosphorus atom was synthesized as an RSSR isomer by covalent self-assembly in the system 1,3-bis[(pyridin-2-yl)phosphino]propane–formaldehyde–isopropylamine.