Study of Organic Self-Assembled Nanosystems by Means of High-Frequency ESR/ENDOR: The Case of Oil Asphaltenes


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Abstract

An approach to investigate self-assembly of oil disperse systems based on high-field electron nuclear double resonance has been suggested. As exemplified by asphaltenes, the oil components most prone to self-assembly, the formation of planar rather than multilayer structures has been directly evidenced experimentally. The suggested method can be applied to elucidate the self-assembly mechanism in wide range of organic objects.

About the authors

M. R. Gafurov

Kazan (Volga Region) Federal University

Author for correspondence.
Email: marat.gafurov@kpfu.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008

I. N. Gracheva

Kazan (Volga Region) Federal University

Email: marat.gafurov@kpfu.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008

G. V. Mamin

Kazan (Volga Region) Federal University

Email: marat.gafurov@kpfu.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008

Yu. M. Ganeeva

Kazan (Volga Region) Federal University; Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center

Email: marat.gafurov@kpfu.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008; ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

T. N. Yusupova

Kazan (Volga Region) Federal University; Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center

Email: marat.gafurov@kpfu.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008; ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

S. B. Orlinskii

Kazan (Volga Region) Federal University

Email: marat.gafurov@kpfu.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008


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