Regiochemistry of Deoxygenation of Nitro-Containing Isatins with Tris(diethylamino)phosphine


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Abstract

Isatin derivatives containing a 4-nitrophenyl group in the side chain or a nitro group in the aromatic fragment reacted with tris(diethylamino)phosphine to give the corresponding isoindigo derivatives with high yields and chemoselectivity.

About the authors

A. V. Bogdanov

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center

Author for correspondence.
Email: abogdanov@inbox.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

D. A. Tatarinov

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center

Email: abogdanov@inbox.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088

V. F. Mironov

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center

Email: abogdanov@inbox.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088


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