Pd–Cu-Catalyzed Synthesis of Alk-5-en-7-yn-2-ones


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Abstract

Stereoselective synthesis of (E)- and (Z)-alk-5-en-7-in-2-ones was performed by cross-coupling of alkynes with 6-chlorohex-5-en-2-one stereoisomers in the presence of PdCl2(PrCN)2 complex and CuI in piperidine.

About the authors

R. N. Shakhmaev

Ufa State Petroleum Technological University

Author for correspondence.
Email: shakhmaevrn@gmail.com
Russian Federation, ul. Kosmonavtov 1, Ufa, 450062

A. Sh. Sunagatullina

Ufa State Petroleum Technological University

Email: shakhmaevrn@gmail.com
Russian Federation, ul. Kosmonavtov 1, Ufa, 450062

E. A. Abdullina

Ufa State Petroleum Technological University

Email: shakhmaevrn@gmail.com
Russian Federation, ul. Kosmonavtov 1, Ufa, 450062

V. V. Zorin

Ufa State Petroleum Technological University

Email: shakhmaevrn@gmail.com
Russian Federation, ul. Kosmonavtov 1, Ufa, 450062


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