Chemical and Electrochemical Syntheses, Structure, and Luminescent Properties of Zinc and Cadmium Complexes with N-{2-[(E)-(4-tert-Butylphenyl)iminomethyl]phenyl}-4-methylbenzenesulfonamide
- Authors: Lifintseva T.V.1, Burlov A.S.2, Vlasenko V.G.3, Koshchienko Y.V.2, Mal’tsev E.I.4, Dmitriev A.V.4, Lypenko D.A.4, Trigub A.L.5, Garnovskii D.A.6
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Affiliations:
- Chemical Faculty
- Research Institute of Physical and Organic Chemistry
- Research Institute of Physics
- A.N. Frumkin Institute of Physical Chemistry and Electrochemistry
- “Kurchatov Institute” National Research Centre
- Southern Scientific Center
- Issue: Vol 88, No 10 (2018)
- Pages: 2125-2132
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222481
- DOI: https://doi.org/10.1134/S107036321810016X
- ID: 222481
Cite item
Abstract
New Zn(II) and Cd(II) complexes with N-{2-[(E)-(4-tert-butylphenyl)iminomethyl]phenyl}-4-methylbenzenesulfonamide were synthesized by chemical and electrochemical methods. The ligand and metal complexes were characterized by the methods of IR, 1H NMR, electron absorption spectroscopy, and X-ray absorption spectroscopy and by quantum chemical calculations. Electroluminescent devices with zinc and cadmium complexes were fabricated as emitter layers, which showed radiation brightness of 460 cd/m2 (15 V) with a maximum at 502 nm and 140 cd/m2 (15 V) with a maximum at 535 nm, respectively.
Keywords
About the authors
T. V. Lifintseva
Chemical Faculty
Author for correspondence.
Email: ltv47@yandex.ru
Russian Federation, Rostov-on-Don
A. S. Burlov
Research Institute of Physical and Organic Chemistry
Email: ltv47@yandex.ru
Russian Federation, Rostov-on-Don
V. G. Vlasenko
Research Institute of Physics
Email: ltv47@yandex.ru
Russian Federation, Rostov-on-Don
Yu. V. Koshchienko
Research Institute of Physical and Organic Chemistry
Email: ltv47@yandex.ru
Russian Federation, Rostov-on-Don
E. I. Mal’tsev
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry
Email: ltv47@yandex.ru
Russian Federation, Moscow
A. V. Dmitriev
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry
Email: ltv47@yandex.ru
Russian Federation, Moscow
D. A. Lypenko
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry
Email: ltv47@yandex.ru
Russian Federation, Moscow
A. L. Trigub
“Kurchatov Institute” National Research Centre
Email: ltv47@yandex.ru
Russian Federation, Moscow
D. A. Garnovskii
Southern Scientific Center
Email: ltv47@yandex.ru
Russian Federation, Rostov-on-Don
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