Email this article Effect of the Solvent on the Coordination of Pyridine Derivatives with Zn Tetraphenylporphine
- Authors: Andreev V.P.1, Sobolev P.S.1, Zaitsev D.O.1, Timofeeva S.M.2
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Affiliations:
- Petrozavodsk State University
- Moscow Institute of Fine Chemical Technologies
- Issue: Vol 88, No 10 (2018)
- Pages: 2108-2113
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222476
- DOI: https://doi.org/10.1134/S1070363218100134
- ID: 222476
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Abstract
The coordination of zinc(II) tetraphenylporphine with pyridines was studied by electronic spectroscopy. Linear correlations were found between the thermodynamic and kinetic parameters of coordination in different solvents. The effect of the solvent on the stability constants of the complexes and the thermodynamics of complex formation are discussed.
About the authors
V. P. Andreev
Petrozavodsk State University
Author for correspondence.
Email: a-alex@rkmail.ru
Russian Federation, pr. Lenina 33, Petrozavodsk, 185910
P. S. Sobolev
Petrozavodsk State University
Email: a-alex@rkmail.ru
Russian Federation, pr. Lenina 33, Petrozavodsk, 185910
D. O. Zaitsev
Petrozavodsk State University
Email: a-alex@rkmail.ru
Russian Federation, pr. Lenina 33, Petrozavodsk, 185910
S. M. Timofeeva
Moscow Institute of Fine Chemical Technologies
Email: a-alex@rkmail.ru
Russian Federation, Moscow
