Email this article Unusual Reaction of Sodium 1,6-Dioxo-2,4-alkadiene-3,4-diolates under Acid Hydrolysis Conditions
- Authors: Mukovoz P.P.1, Slepukhin P.A.2,3, Ganebnykh I.N.2,3, El’tsov O.S.3, Danilova E.A.4
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Affiliations:
- All-Russian Research Institute of Phytopathology
- Postovskii Institute of Organic Synthesis
- Ural Federal University named after the first President of Russia B. N. Yeltsin
- Ivanovo State University of Chemistry and Technology
- Issue: Vol 88, No 10 (2018)
- Pages: 2039-2043
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222463
- DOI: https://doi.org/10.1134/S107036321810002X
- ID: 222463
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Abstract
The reaction of sodium 1,6-dioxo-2,4-alkadiene-3,4-diolates with HCl solution afforded unexpected hydrolysis products, namely (2Z)-2-hydroxy-4-oxobut-2-enoic (2,4-dioxobutanoic) acid esters. The structural features of the synthesized compounds were discussed on the basis of IR, 1H NMR spectroscopy, mass spectrometry and X-ray diffraction analysis data.
About the authors
P. P. Mukovoz
All-Russian Research Institute of Phytopathology
Author for correspondence.
Email: mpp27@mail.ru
Russian Federation, ul. Institut 5, Bol’shiye Vyazemy, Moscow oblast, 143050
P. A. Slepukhin
Postovskii Institute of Organic Synthesis; Ural Federal University named after the first President of Russia B. N. Yeltsin
Email: mpp27@mail.ru
Russian Federation, Yekaterinburg; Yekaterinburg
I. N. Ganebnykh
Postovskii Institute of Organic Synthesis; Ural Federal University named after the first President of Russia B. N. Yeltsin
Email: mpp27@mail.ru
Russian Federation, Yekaterinburg; Yekaterinburg
O. S. El’tsov
Ural Federal University named after the first President of Russia B. N. Yeltsin
Email: mpp27@mail.ru
Russian Federation, Yekaterinburg
E. A. Danilova
Ivanovo State University of Chemistry and Technology
Email: mpp27@mail.ru
Russian Federation, Ivanovo
